Squadron green putty was my choice of filler but I became disillusioned with the shrinkage over time (many months). This was a thickness of less than 1 mm, causing very fine joins in the coach roof to open up and look untidy long after the car was completed.
I prefer Tamiya Putty now as it applies nicely and sands very smoothly. I remember years ago that the ‘finescale’ modellers would use superglue to fill joins. The area would be sanded within 30 minutes before the superglue could harden sufficiently.
As regards carcogenic properties of the different chemicals we use, well it is proven that just about anything in our environment can prove harmful. Your bacon and eggs for breakfast have been shown to cause cancer. Overcooked steak, sausages, toast, etc., is also carcogenic along with diesel fuel and timbers such as western red cedar. Any timber with anti-fungal rot properties is suspect as the natural insect resisting chemicals in the timber are known to cause cancer.