The vacuum pump isn’t required, it does make things easier, but if your careful you’ll make perfect molds with out it.
What you’r wanting to make is the perfect things to get started on.
Rule #2: ANY CASTING WILL ONLY BE AS GOOD AS THE ORIGINAL YOU START WITH!!!
Keeping that in mind, we tend to use the 3’ or 5’ or 10’ rule a lot in the garden. I wouldn’t spend a ton of time on a master for something that won’t be seen up close. OTOH detail parts on a show piece, needs to be perfect.
You can make the master out out of any thing that’s not porous. At this experience point I wouldn’t suggest trying anything to complex yet, keep it simple without any undercuts or complex shapes. Finnish is important on the master (Rule #2). If in doubt you should seal the master with a light coat of clear acrylic spray. The RTV won,t stick to most things, except itself, glass, and a few other things, unless they are porous like wood, and it doesn’t stick to the wood, it kinda soaks into the openness of the surface. The RTV (Room Temperature Vulcanizing) will pick up an incredible amount of detail from the master. So if you want a wood grain on the final piece, make the master out of wood, but seal it before molding.
I haven’t used that particular kit, but they are mostly all alike and will do just fine for starters. You must follow the mixing directions for that kit… When the time comes to pour the mold.
Time to make the master!