Hello John.
I can give you an opinion based upon my 20+ years experience handling most types of batteries and Large Scale locos.
I have no vested interest in any of the chemistries.
I do make a NiCd trickle charger but I don’t really care if sell any more of them or not.
NiCd.
I use and recommend NiCd batteries only where a relatively high current draw is required. Specifically Sub C cells made up into packs of a suitable voltage.
Whilst I acknowledge NiCd cells can develop a memory if ram charged when only partially discharged, my experience is that the momory effect does NOT happen provided;
a) you charge them at the recommended 10% rate for the recommended period of time. It has been my experience they can be left on the 10% charger for a extended period without any ill effects.
b) you use a proper peak detection charger if you want to fast charge them.
Method A ensures the longest life possible as in the number of recharges possible. Typically NiCd batteries will give approximately 1,000 recharges.
If they are good quality they will also recover even after being let run flat and stay there.
Just this weekend I charged up a 12 volt pack of Medical grade Sub C NiCd’s that had been left discharged and idle for over 2 years.
They do have a downside. NiCd batteries use a very toxic chemical in their construction and MUST be disposed of correctly when the have expired. Cadmium is dangerous.
NiMh
These have a greater energy density than NiCd but only have half the life span of NiCd. 500 recharges versus 1,000
The big downside to me is they self discharge rapidly such that some packs will be flat 2 weeks after charging.
Most people notice this in digital cameras. Very annoying. A new type of hybrid cell to overcome this is now available in AA size. See below.
Like NiCd cells, NiMh can be made up into pretty well any voltage and shape you can imagine.
They are not toxic.
Cell sizes.
I can only speak from experience of SubC, AA and AAA size batteries. I know a whole variety of sizes are available, but not here in Australia. Well, not easily and certainly not cheaply.
Sub C and AA/AAA cells are constructed differently. Better quality Sub C are designed to handle high charge/discharge currents. AA/AAA cells are not. AA in particular are rated at only 500 ma max current draw. Any more put in or taken out will likely severely reduce their life span. I know. At my cost I have had to replace AA battery packs that did not last under warranty.
Sanyo and Panasonic have a new hybrid chemistry available in AA size that combines NiMh and Alkaline to make a batery that is guaranteed to hold 85% charge for 1 year. Sanyo cells are branded ENELOOP.
However, they are still limited by the amount of current in and out. Even though big in capacity that capacity is designed for a low draw for a long time - v - high draw for a short time. They are brilliant in my digital camera.
I have supplied some packs with loco installations with, so far, excellent results.
Lead Acid Gel Cells
I have never had any success with gel cells. Others swear by them. I just swear at them.
They only come in two voltages, 6v and 12v. They are big, heavy and awkward to fit in small locos. They drop their voltage as they discharge and will die rapidly if not kept charged.
However, they are cheap. At least the low quality ones are.
The high quality Deep discharge types are not cheap.
Even when looked after, car batteries last only a couple of years unless you buy the better quality and much more expenisve types.
Li-Poly/Li-Ion
I have no personal experience with either of these other than the batteries in my cell phones, which have been excellent.
My last digital camera ate these batteries. 18 months and they were dead, no matter what.
There have been many instances of these blowing up and catching fire in hobby use. Even when they have the built in circuitry to regulate their use.
Crest sell a 21.5 volt pack that is reportedly safe to use.
Personally I would still be wary of them for now.
Taking into account value for money and the size/capacity ratio, Sub C Ni-Cd cells win hands down for our Large Scale use.
If space is a problem and the loco has alow current draw, I can recommend Sanyo ENELOOPP AA cells.
I hope that information is of use.