Just a follow up on the final outcome of my battery issue.
I separated the 2 batteries and connected them to a DPDT switch which then selects either pack as required, as suggested by TOC and Tony. I did not go with the centre off because that would have meant that I would effectively have had 2 Off switches in series.
I found when I separated that there was a voltage difference of 0.01V between them (measured 15.02 and 15.01V) but when I connected them into the circuit their voltages dropped to about 8V so I suspect they had discharged to nearly flat. So one is happily being charged as I write this and I will test further.
Regarding chargers I have 2 “Master Instruments” universal NiCd/NiMH chargers and a Turnigy Accucel 6, all auto detect the number of cells and I set the max charge current (usually C/10 or approx. one tenth of capacity) and they switch off when the batteries are charged and maintain a trickle till disconnected. They all apply current in short bursts at least that is what is indicated on the meters/display and judging by the power supply that feeds them (an ATX PSU), loading change ( fan speed changes) that is what is happening
I have no real idea how they work I just know they do what I want and that is all I ask of them.
Thanks for all the information about batteries, it was way more than what I expected but I can now use this as a reference for the future.
I have had another brainwave of using a “Picaxe” microcontroller to monitor the battery pack voltages and auto switch between them via a relay when one is getting low, but that, as they say, is a story for another time.