Steve is right with one caviat… he is refering to rotary dump unit trains. There are unit coal trains that do not have rotaries. And there are unit coal trains without rotary couplers which are broken up car by car to be rotary dumped anyways. (I have personally seen this happen so it isn’t just rumor)
NS has a fleet of rapid discharge hopper which have a large… paddles for lack of a better term, which when depressed by a stationary trackside object will cause all hopper doors to unlock and drop open.
A&B ends on a singular freight car are used to denote the location of things. The B end is always the end with the hand brake. If a train has a defect (such as a hotbox), the detector identifies it as the X axle in the train. But once the car is setout and tagged with “hotbox on axle #3” the carmen need to know which end is the ed we counted from. This is a standard set by the railroads.
On articulated cars, the platforms are identified as A-C-D-E-B, for continuity with the AB ends on a single car. However, on 3-packs, there is usually only one handbrake, and the brakes on the entire car are usually actuated from only a single control valve. On 5-packs, there is usually a hand brake at both ends (in which case the AB is used primarily for identification purposes) and there is 2 or 3 control valves, depending on car design.
As for terminology, that is highly dependent upon the road you are on. About the only rules which translate from one road to another are “Clear (Signal)”, “Rule G” and “Restricted Speed”.
On my territory (two different divisions of NS) ALL remote control moves are considered shoving moves, even if the engine is on the leading end.
As for HAZMAT placement, there are a ton of placement regulations concerning contents of cars: how far they have to be from engines/cabooses/passenger cars, either endof the train, other HAZMAT, etc. This is standardized across the nation so that trains from one line don’t cross onto another road and have to be switched around, but also because of uniform emergency response needs.